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The orientation of the atoms between individual grains varies, so at the boundaries of the grains—where each one touches the next—there are inconsistencies in the way the atoms are stacked. More abrasive damage will occur with frequent or vigorous polishing or if hard abrasive compounds are used. Figures 56a and 56b. For display cases and storage cabinets, achieving low air infiltration means minimizing holes and cracks (any crack or hole should be so tiny as to be difficult to see with the naked eye), plus having joints and gasketing close-fitting enough so that a normal sheet of paper cannot be slipped into any of the joints. A student investigates a pure metal x.com. Similar damage also occurs when salt contaminates a metal: if moisture is present, the salts hydrate and increase in volume, thus fracturing the cohesion of the surface layers and causing losses. Emissions from cellulose nitrate films: 4000. Active corrosion: Zinc surfaces corrode and form white corrosion products when exposed to water or high levels of humidity.

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Caring for Historic Longarms: Storage and Handling Requirements. A patina may occur naturally as a result of long-term exposure to weather, pollution, etc., or it may be artificially induced through the application of various chemicals. It is important to realize that: - A tarnished surface is stable and does not need to be polished. The air sent through the filtering system is a mixture of outdoor air and recycled indoor air, its ratio changing depending on outdoor temperature and visitor density. Measuring cylinder, 100 cm3. Dry storage for corroding iron objects. In museum collections, the chief ones encountered in any quantity are aluminum, copper, gold, iron, lead, nickel, silver, tin and zinc. Scavenger: - Synonym of pollutant sorbent. Metals can be artificially finished or patinated with a variety of chemical and physical techniques, and it is important to identify these original finishes from other possible surface layers. Degrading cellulose acetate (vinegar syndrome). A student investigates a pure metal x 10. The safest kind to use on metals, especially polished ones, are disposable nitrile gloves made without chemical accelerators (e. N-DEX Free nitrile gloves).

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Controlled heating will cause the grains to return to a more uniform shape, thus softening the metal; this process is called "annealing. This is one case where time has simply polished the advice! After a short time the students observe that the bottom of the beaker is frozen to the wood surface. Its most effective use is by wrapping a silver object entirely within it so that the cloth's silver particles sacrificially react first with any outside gaseous sulfur compounds. A loosely inserted cork allows sufficient build-up of gas in a slow reaction to enable a successful test. Tannic Acid Coating for Rusted Iron Artifacts, formerly published under the title Tannic Acid Treatment, revised. Extend your table of observations in your notebook to include these. A student investigates a pure metal x 2. The multi-level approach towards protecting a metal collection from corrosion involves identifying metal objects that are unstable or more at risk in order to provide them with tailored, enhanced protection. Metal foil laminates (usually made of an aluminum core with a plastic layer on each side, e. Marvelseal) are generally the most effective barrier material, but they have the disadvantage of not being transparent. Examples of silver-plated objects include flatware, serving dishes, jewellery, liturgical objects, candlesticks and trophies. Old friends are coming for dinner and the silver candlesticks they gave us for a wedding present are about to be used for the first time in years.

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A microenvironment is usually created through the use of an enclosure (a container made of a barrier material assembled with tight seals) in which is included one or more specialized products (e. desiccant, sorbent). For each of the following common metals, its typical corrosion product colour is listed, and the appearance of both its stable corrosion surface and its actively corroding surface(s) is described. During the process of working a metal, the grains become distorted, resulting in hardening. Climate control for the building's interior can be achieved by using an active mechanical system (i. a building's HVAC system), if the institution has one, and using passive means via improvements to the building fabric (i. repairs to prevent risk of water ingress, improved insulation and airtightness). RH has a major influence on the degree of corrosion that pollutants and contaminants can cause. Selwyn, L. Lead in Museum Collections and Heritage Buildings. The teacher asks the students to make a claim about the observation and to justify their claims. If problems are identified, proceed to correct the conditions or to enhance the level of protection specifically for the objects requiring it. Silver storage cabinets. Activated alumina impregnated with potassium permanganate: it has very good sorption performance for hydrogen sulfide; good performance for sulfur dioxide, acetic acid and ozone; and medium performance for nitrogen dioxide. Silver, for example, is frequently electroplated onto copper and copper-nickel alloys (Figures 5a and 5b).

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Also, brand new cotton gloves contain residual chloride from processing, so they need to be washed prior to use. In particular, document the extent of corrosion present, and monitor any outbreak of corrosion. Protect metal objects from dust deposits using enclosures, when possible (consult Enclosures), and dust sheets. CCI Note 9/6 Care and Cleaning of Iron.

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Examples of common alloys in collections are brass (copper and zinc), bronze (copper and tin), steel (iron plus carbon, manganese, nickel, chromium, etc. Basic RH control strategies include the following: - Keeping objects away from colder areas in a room (e. exterior walls with windows) because these will cause localized, damp pockets of air and result in higher corrosion risks for metal objects. They are usually thicker and more uneven on archaeological objects than on non-archaeological ones. Apply sparingly, then rub the surface of the object well with a soft cloth to distribute the oil evenly and remove excess. Care and Cleaning of Iron, revised.

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This kind of physical damage or material losses may be due to recent corrosion that has formed at the metal layer under the surface, thus causing an expansion in volume that pushes against the overlying material (such as older corrosion products, paint or plating layer) and causes cracks and flaking. Some specialized plastic laminates (e. Escal films) are virtually as effective and are transparent — but they are also expensive. In H. Whelchel, ed., Caring for Your Collections. If needed, enhance protection using activated charcoal. The selection of metals can vary according to what is available as small granules (up to 5 mm), coarse filings or foil.

Polishing compounds are often acidic or alkaline. Which of the following is the best claim and justification based on the students' observation? Salt-contaminated copper and its alloys are only at low risk of corrosion if kept below 42% RH. For example, sulfur compounds cause silver to tarnish (consult Understanding how silver objects tarnish for more information). Mild steel, cast iron. With regards to display cases, this has design implications.